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You can use the vertical bar ('|') to differentiate between label and value.
If you use a pipe character ('|') in an option value, the part before the pipe will be used as the label and the part after the pipe will be the actual value.
You can use this method in a Please select, Radio buttons and Box fields.
The backend will look like this:
And the interface will look like this:
Learn more about the form widget and its options here.